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        <title><emph>How to Make Salt from Sea-Water:</emph>
Electronic Edition.</title>
        <author>LeConte, John, 1818-1891</author>
        <funder>Funding from the Institute of Museum and Library
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        <pubPlace>University of North Carolina at Chapel Hill, </pubPlace>
        <date>1999.</date>
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          <titleStmt>
            <title type="title page"> HOW TO MAKE SALT FROM SEA-WATER.</title>
            <author>Professor John LeConte</author>
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              <resp>Published by the</resp>
              <name>Governor and Council of South Carolina</name>
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          <extent>      p. 10.</extent>
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            <pubPlace>Columbia, S. C.:</pubPlace>
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            <date>1862</date>
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            <item>Seawater -- Distillation -- Confederate States of
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            <item>Saline water conversion -- Confederate States of
America.</item>
            <item>Saline water conversion -- Distillation process --
Confederate
States of America.</item>
            <item>Manufacturing process -- Confederate States of
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    <front>
      <div1 type="cover">
        <p>
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      </div1>
      <div1 type="title page">
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      <titlePage>
        <docTitle>
          <titlePart type="main">HOW TO MAKE SALT<lb/>
FROM SEA-WATER.</titlePart>
        </docTitle>
        <byline>BY</byline>
        <docAuthor>PROFESSOR JOHN LECONTE.</docAuthor>
        <docImprint>
<publisher>PUBLISHED BY THE
<lb/>GOVERNOR AND COUNCIL OF SOUTH CAROLINA.</publisher>
<pubPlace>COLUMBIA, S. C.:</pubPlace>
<publisher>CHARLES P.  PELHAM, STATE PRINTER.</publisher>
<docDate>1862.</docDate>
</docImprint>
      </titlePage>
    </front>
    <body>
      <div1 type="text">
        <pb id="lecon3" n="3"/>
        <head>MANUFACTURE OF SALT FROM SEA-WATER.</head>
        <div2 type="method">
          <head>FIRST METHOD.</head>
          <head>BY THE SPONTANEOUS EVAPORATION OF SEA-WATER IN LARGE SHALLOW<lb/>
BASINS, CALLED  “SALT GARDENS,” OR “ SALINES.”</head>
          <p>The process is simple, and requires but little apparatus of any kind. The first
condition for the establishment of a “saline” is a low, broad, level ground on the border
of the sea, bay, or inlet, which can be protected by dykes or dams from the action of the
tides. A shallow <hi rend="italics">artificial pond</hi>, or <hi rend="italics">reservoir</hi> is made near the sea, and, if possible, <hi rend="italics">below</hi>
the level of high tides: so that it may receive water from the sea at high tides, by means
of flood-gates. When, however, it is <hi rend="italics">above</hi> the sea-level, the water may be elevated by
means of hydraulic machines. The bottom of the <hi rend="italics">pond</hi> or <hi rend="italics">reservoir</hi> must be laid out
perfectly <hi rend="italics">even</hi>, the soil must be <hi rend="italics">clayey</hi>, to retain the water, and should be beaten hard and
smooth. Its outline may be irregular, and its depth should be from three to six feet. Of
course its size must depend on the extent of the “saline” which is to be established. In this
reservoir the sea-water deposits its sediments, becomes warmed by the sun's rays, and
begins to evaporate.</p>
          <p>From this reservoir the partially concentrated brine is led by a canal to a series of
“rectangular basins,” No. 1, from ten to sixteen inches in depth.
These “basins” are divided into a series of compartments, by means of little cross
banks, through which the brine flows successively, in a slow current, which can be
regulated at pleasure. These “basins” should be carefully prepared like the “reservoir,” so
as to retain water. Here, by the action of the sun and wind, the water is rapidly
evaporated, and deposits a portion of its <hi rend="italics">lime</hi>, in the form of sulphate. When the
concentrated brine marks 15° to 18° of Baumé's hydrometer, it deposits a considerable
quantity of sulphate of lime; and when it marks 25°, the <hi rend="italics">whole</hi> of the lime is deposited.</p>
          <p>From “basins” No. 1 the brine passes, in like manner, to another series of similar
“rectangular basins,” No. 2, larger and more shallow, but more carefully constructed. In
these “basins,” No. 2, the remainder of the sulphate of lime is deposited, and the evaporation is carried to such a point 
<pb id="lecon4" n="4"/>
that the water becomes a <hi rend="italics">saturated brine</hi> by the time it reaches the <hi rend="italics">lower</hi> side of them. At
this period the volume of the concentrated brine is greatly diminished, and, marking 25° of Baumé's hydrometer, is ready to be transferred to the “salting tables.”</p>
          <p>From “basins” No. 2 the concentrated brine passes, in like manner, to a <hi rend="italics">third</hi> and <hi rend="italics">last</hi>
series of similar “rectangular basins,” No. 3, called “<hi rend="italics">salting tables</hi>.” These are smaller and
shallower “basins,” carefully constructed, and divided into compartments communicating
with each other, and the layer of water should not be more than three inches in depth.
The point at which the brine has reached a sufficient degree of concentration to be
introduced into the “salting tables,” is sometimes judged of by the water becoming RED,
but the hydrometer is, perhaps, a more reliable indicator—it should mark 25° of Baumé.
In the “salting tables” the brine soon begins to deposit salt, in the form of crystalline
crusts, which are either collected with rakes as soon as they form, or allowed to
accumulate at the bottom, until they form masses of several inches in thickness. The
brine on the “tables” is renewed daily, or every two days, according to the evaporation;
whilst the “reservoir,” as well as “basins” No. 1 and No. 2, are constantly supplied with
fresh brine. The concentration of the brines in the “salting tables” must be carefully
watched, and their density never allowed to <hi rend="italics">exceed</hi> 28 1/2° of Baumé's hydrometer,
otherwise a deposit of sulfate of magnesia (Epsom salts) would be formed, rendering the
salt impure. The <hi rend="italics">mother-liquors</hi>, as they are called, are run off as soon as they have
reached the above density: it is usually necessary to draw them off three or four times
during the season. When the salt has attained a sufficient thickness, it is broken up and
piled upon the sides of the “tables” in large pyramids, which are covered with clay. In
these heaps the salt undergoes a process of <hi rend="italics">purification</hi>—the moisture from the clay, or
from occasional rains, penetrates slowly through the mass, removing the more soluble
foreign matters, and leaving the salt much purer than before. If the salt in these heaps is
too much soiled to be sent into market, it requires a process of <hi rend="italics">refining</hi>. For this purpose
<hi rend="italics">two</hi> methods are employed; the <hi rend="italics">one</hi> consists in simply <hi rend="italics">washing</hi> the crude salt with a
concentrated brine, which removes the foreign salts, and a large portion of the earthy
impurities. The <hi rend="italics">other</hi>, more perfect, but more <hi rend="italics">costly</hi> process, consists in dissolving the
impure salt in water, and adding a little lime to precipitate the salts of magnesia, always
present, after which the filtered brine is slowly evaporated, to obtain the large-grained
salt used for salting provisions. When the “salines“ yield the <hi rend="italics">coarsely crystalline
“bay-salt,” there is no need of these refining processes</hi>.</p>
          <p>At some of the French “salines” the concentration of the brines is carried as far as 32° of
Baumé's hydrometer, and the <hi rend="italics">salt separated into three</hi>
<pb id="lecon5" n="5"/>
<hi rend="italics">qualities</hi>.  Between 25° and 26° of Baumé, the brine deposits 25 per cent. of the salt
extracted, which is kept apart, on account of its great purity, and sold at a higher price
than the rest. In passing from a density of 26° to 28 1/2° of Baumé, 60 per cent. more of
salt of second quality is deposited, and from this point to 32° the remaining 15 per cent. is
obtained, somewhat impure and deliquescent, from the magnesian salts which it contains,
but preferred for the salting of fish, on account of its tendency to keep them moist.</p>
          <p>The “salines” are usually cultivated from March to September, so that the process is
suspended during a large part of the year. But the French have recently introduced
improvements, by which the works are carried on throughout the whole year, with an
increase of the produce by about 50 per cent.  During the months of autumn the
evaporation is still carried on, though more slowly, and brine is furnished marking from
10° to 20° of Baumé. This is stored away in pits or large wells, where the diluting effect
of the winter and spring rains is but little felt, and at the commencement of the warm
season this brine is elevated into the evaporating “basins,” so that the summer's labors are
commenced with <hi rend="italics">concentrated brine</hi>, and the salt is all harvested in the months of August
and September.</p>
          <p>The foregoing method, when conducted on a large scale, constitutes the most <hi rend="italics">economical</hi>
means of making salt from sea-water. But the nature of our climate offers serious
obstacles to the manufacture of salt by this process: <hi rend="italics">first</hi>, on account of the large quantity
of rain which falls; and <hi rend="italics">secondly</hi>, from the great <hi rend="italics">uncertainty</hi> of having <hi rend="italics">dry weather</hi> after
mid-summer, which is necessary during the deposition of salt on the “salting tables.” In
the moist and rainy climate of Venice these difficulties are in a measure overcome, by so
arranging the “salting tables” that in case of heavy rains the concentrated brines are
rapidly run off into deep reservoirs or large wells, from which they are again elevated
when the weather becomes fine.</p>
          <p>The marsh lands, provided they have an <hi rend="italics">underlying stratum of clay</hi>, might be prepared
for extensive “salines.” In using sea-water of full strength, the proportionate area of the
several evaporating “basins” may be as follows:
<list type="simple"><item>Area of reservoir, 1/3 of total evaporating surfaces.</item><item>Basins No. 1, 1/6 of total evaporating surfaces.</item><item>Basins No. 2, 1/3 of total evaporating surfaces.</item><item>Basins No. 3, 1/6 of total evaporating surfaces.</item></list>
When the water used is <hi rend="italics">one-half</hi> the strength of that in the open ocean, the area of basins
No. 3, the “salting tables,” need not be more than <hi rend="italics">one-tenth</hi> of the aggregate evaporating
surfaces. Whenever it is practicable, the different basins should be nearly on the <hi rend="italics">same plane</hi>, so that the brine may flow from one series to the other, as its level is reduced by
evaporation.
<pb id="lecon6" n="6"/>
But when it is necessary to construct the basins at <hi rend="italics">different levels</hi>, the brines may
be raised from one series to another by means of wooden drums, from eight to
sixteen feet in diameter, moved by steam or horse power.</p>
          <p>The “saline” at Baynas, in the South of France, covers an aggregate area of
nearly 371 acres, and yields per annum 2,125 bushels (56 pounds to the bushel)
of salt to <hi rend="italics">each acre of evaporating surface</hi>. At other French “salines”
the average yearly produce is about 1,594 bushels to each acre of evaporating
surface. At the salt works of the Lake of Berre, near Marseilles, the brine is
scarcely <hi rend="italics">half the strength</hi> of sea-water, and yet the annual yield is 966 bushels of
salt to each acre of evaporating surface. The <hi rend="italics">average price</hi> of salt at the last-named
“salines” <hi rend="italics">is only five cents per bushel</hi>, but an outrageous <hi rend="italics">impost</hi> upon it,
amounting to <hi rend="italics">ten times that sum</hi>, enhances the price to about fifty-five cents per bushel.
At these works the “mother-liquors” are used for the production of large quantities of sulphate
of soda (from which soda is manufactured), as also the salts of potash and
magnesia.</p>
        </div2>
        <div2 type="method">
          <head>SECOND METHOD.</head>
          <head>BY “SALINES” AND ARTIFICIAL EVAPORATION COMBINED.</head>
          <p>In this method, the evaporating basins are constructed as before indicated,
<hi rend="italics">excepting</hi> that basins No. 3 (salting tables) <hi rend="italics">are omitted</hi>. In fact, by <hi rend="italics">enlarging</hi> the
area of basins No. 1, we might likewise dispense with basins No. 2, thus retaining
only the reservoir and the series of basins No. 1 as the aggregate evaporating
surfaces. The sea-water is<hi rend="italics"> first</hi> concentrated in these basins by spontaneous
evaporation, and the brine thus obtained is <hi rend="italics">boiled down</hi>, and the salt extracted. For
this purpose furnaces, evaporating-pans, and a store-house must be provided. The
pan is a shallow four-sided vessel of sheet-iron, from nine to twelve inches deep,
with flat bottom, somewhat deepened towards the middle, and from ten to
twenty feet or more in length and breadth, according to the extent of the salt-works. The bottom of the pan is supported by small pillars of brick-work, built
from the foundation of the furnace, so as to form, at the same time, <hi rend="italics">flues</hi> for the
distribution of the heat. These flues are calculated to disseminate the flame as
uniformly as possible over the bottom of the pan, after which it is made to pass
out behind, to one of the rooms of the store-house, called the drying-chamber,
which it heats, and then escapes by the chimney.</p>
          <p>The process of boiling consists of <hi rend="italics">two </hi>distinct operations: <hi rend="italics">First</hi>, the purification
and evaporation of the brine up to the point of <hi rend="italics">saturation</hi>, which is called
<hi rend="italics">sludging</hi>; and <hi rend="italics">second</hi>, the crystallization of the salt, which is called <hi rend="italics">soccage</hi>.
<pb id="lecon7" n="7"/>
SLUDGING.—The pans are rather more than half filled with clear concentrated brine,
which is brought rapidly to a state of violent boiling, the evaporated portion being
replaced from time to time by <hi rend="italics">fresh brine</hi>. The surface soon becomes covered with a dirty
brown scum, which, with the salts precipitated at the same time, collects as a thick mud.
As far as possible, this must be removed by means of rakes, but some attaches itself to
the bottom of the pans, forming the <hi rend="italics">pan scale</hi>. After twelve or fifteen boilings, it often
increases to the thickness of an inch, and must then be broken up by the chisel and
removed. In the meantime the solution of salt becomes more concentrated by the constant
evaporation and renewal of the brine, until at last it begins to <hi rend="italics">crystallize</hi>. This process
lasts from 20 to 24 hours. When the scum of crystals begins to form on the surface, the
fire is <hi rend="italics">lessened</hi>, until the temperature of the brine falls to 194° or 167° Fahrenheit, when,
with <hi rend="italics">slow evaporation</hi>, the <hi rend="italics">soccage</hi> begins, and lasts <hi rend="italics">several days</hi>.</p>
          <p>SOCCAGE.—During this time the small floating crystals gradually increase in size and
sink to the bottom. When the pan is kept at 194° the crystals have no time for growing,
and fine-grained salt falls to the bottom; at 167° they remain floating a longer time, and
produce salt of a coarser grain. The temperature must not be <hi rend="italics">too much</hi> reduced, otherwise
the chloride of magnesium is a source of obstruction to the process, unless removed by
the addition of sulphate of soda or slaked lime; and, better still, of <hi rend="italics">both</hi>. To remedy the
<hi rend="italics">crusting</hi> of the surface of the brine, which sometimes occurs, a half an ounce of <hi rend="italics">butter</hi>, or
a small quantity of <hi rend="italics">powdered rosin</hi>, may, if necessary, be added to the pan. Sometimes
the <hi rend="italics">sludging</hi> and <hi rend="italics">soccage</hi> are conducted in <hi rend="italics">separate</hi> pans, the brine being transferred at
the proper time.</p>
          <p>The <hi rend="italics">purity</hi> of the salt diminishes towards the end of the process of <hi rend="italics">soccage</hi>; for this
reason it must be stopped before all the salt is deposited. It need not, however, be rejected
at the end of each boiling; a <hi rend="italics">second</hi>, and sometimes even a <hi rend="italics">third</hi>, charge may be boiled
down before the residue—the mother-liquor—is removed.</p>
          <p>During the whole process of <hi rend="italics">soccage</hi> the salt is raked up from the bottom with
long <hi rend="italics">cullender-shovels</hi>, to the edge of the pan, and placed either in wicker-baskets of
peeled willow, or heaped upon boards which are thrown back for the purpose, when, in
both cases, the brine runs back to the pan. The moist salt, either in the same baskets or
spread out upon <hi rend="italics">hurdles</hi>, is then placed in the drying-chamber, where it is exposed to a
heat of 120° or 130° Fahrenheit as long as it loses moisture, when it is packed up for sale.</p>
          <p>At Lymington, in Hampshire, England, the process of obtaining salt from sea-water is
similar to the foregoing, but somewhat <hi rend="italics">simpler</hi>. The sea-water is concentrated, by
spontaneous evaporation, in shallow basins, to about
<pb id="lecon8" n="8"/>
<hi rend="italics">one-sixth its bulk</hi>, before admitting it into the boilers. The salt is not <hi rend="italics">fished</hi> out of
the pan and drained in baskets, but the water is almost entirely evaporated, and
the whole mass of salt taken out at once, and removed to troughs with holes in the
bottom: through these it drains into pits under ground, which receive the mother-
liquor. Under the troughs, and in a line with the holes, are fixed upright stakes (old
broom-handles), and on these the salt concretes and forms, in the course of ten or
twelve days, on each stake a mass of sixty or eighty pounds. These lumps are
called <hi rend="italics">salt-cats</hi>. They bear the proportion to the salt made from the same brine of
one to one hundred. The mother-liquor is reserved for the manufacture of Epsom
salt during the winter season.</p>
          <p>COST OF BOILING.—This will, of course, depend on the extent to which the
brine has been concentrated by the process of natural evaporation in the basins. If
practicable, the brine should mark about 20° of Baumé before it is introduced into
the boilers. To do this, ordinary sea-water must be evaporated to about <hi rend="italics">one-eighth</hi>
of its bulk. Calculation shows that 10,000 gallons (of 231 cubic inches <hi rend="italics">each</hi>) of
this concentrated brine contains 305 1/2 bushels (of 56 pounds) of salt. Assuming
that only <hi rend="italics">eighty-five per cent</hi>. of it can be conveniently extracted, this quantity of
brine should yield nearly 260 bushels of salt. With tolerably good arrangements
for boiling, <hi rend="italics">each pound of wood should evaporate</hi> 3 1/2 <hi rend="italics">pounds of water</hi>. Taking
the weight of a cord of <hi rend="italics">dry pine</hi> to be equal to 3,200 pounds (a <hi rend="italics">low</hi> estimate), it
will require about 7 1/3 cords to boil down the 10,000 gallons so as to extract the
260 bushels of salt; that is, it will require the burning of <hi rend="italics">one cord</hi> of wood to
every 35 1/2 bushels of salt manufactured.</p>
          <p>Supposing the concentration of the sea-water to be carried only as far as at
Lymington, viz: to <hi rend="italics">one-sixth</hi> of its bulk, or marking 15° of Baumé, 10,000 gallons
will contain about 194 1/2 bushels of salt capable of being extracted. In this case
about 26 1/2 bushels of salt ought to be made for each cord of wood burnt.</p>
        </div2>
        <div2 type="method">
          <head>THIRD METHOD.</head>
          <head>BY SPONTANEOUS EVAPORATION IN GRADUATION-HOUSES AND 
BOILING <lb/>COMBINED.</head>
          <p>The advantages of this method are: 1. That all the processes are conducted <hi rend="italics">under
shelter</hi>, so that the operations are independent of <hi rend="italics">rainy weather</hi>. 2. That the <hi rend="italics">space</hi>
required for the works is comparatively <hi rend="italics">small</hi>. 3. That the arrangements are <hi rend="italics">not
costly</hi>, and may be put up on any desired scale.</p>
          <p>A large reservoir is constructed at some point conveniently situated for
receiving the brine from the sea. From this the sea-water is pumped up
<pb id="lecon9" n="9"/>
into a large wooden cistern on the top of a tower 25 or 30 feet in height, from
whence it is conducted to the graduation-house, to be concentrated.</p>
          <p>GRADUATION-HOUSE.—This is a long, open frame building, the longest
side of which is exposed to the prevailing wind of the locality. The floor of the
building is made of a large clay basin, or of strong wooden planks, intended to
collect the brine which has been concentrated by evaporation. The spaces
between the frame of the shed are filled with bundles of twigs or fagots, so that the
building looks like a vast wall of <hi rend="italics">brush</hi>, 20 or 30 feet high, and from 100 to 1,000
feet in length. The pyramid of fagots should be ten feet thick at its base and six
feet at its upper part. Under the ridge of the graduation-house, and consequently
<hi rend="italics">over</hi> the middle of the long wall of fagots, is a long wooden trough or spout,
perforated with holes at small intervals, through which the sea-water flows
from the large cistern on the tower. In this manner the weak brine is made to fall
like a perpetual shower over the vastly extended surface of the fagots into the
basin below, during which it is rapidly concentrated by evaporation. This
partially concentrated brine is again pumped up, and undergoes the same operation
successively, until it is sufficiently concentrated for boiling. The same
brine is usually passed four or five times through the fagots before it is fit for boiling;
it is then passed into a reservoir, and kept for the boiling operations. During these
successive concentrations the fagots gradually become coated with a <hi rend="italics">crust</hi> of the
salts of lime, but one set will last about eight or ten years.</p>
          <p>Of course it is best that this operation should be conducted during the warm
season; in fact, when the temperature is below 27° Fahrenheit, a portion of salt is
<hi rend="italics">lost</hi> by the reaction of the sulphate of magnesia. But the boiling may be carried on
at any season. In general, the <hi rend="italics">brine fit for boiling</hi> should contain about 20 per
cent. of salt, that is, should mark 20° of Baumé. The boiling process is the same
as that indicated in the <hi rend="italics">second method</hi>, and its <hi rend="italics">cost</hi> will be as there estimated.
By adding <hi rend="italics">slaked lime</hi> to the reservoir of brine fit for boiling, the magnesia might
be precipitated, and a purer salt obtained.</p>
        </div2>
        <div2 type="method">
          <head>FOURTH METHOD.</head>
          <head>BY LIXIVIATING SALINE SAND AND THEN BOILING THE BRINE.</head>
          <p>This method is employed in Lower Normandy, and is used for making salt
on a <hi rend="italics">small scale</hi>. A level shore with a clean sand is selected, and the necessary
buildings are erected (covered sheds, evaporating-pans, store-houses, &amp;c.), and an
area of three or four acres is chosen, a little <hi rend="italics">below</hi> the level of spring tides. The
surface is carefully levelled, and rolled smooth and hard. It is then filled with
sand taken from the shore at low water, to 
<pb id="lecon10" n="10"/>
the depth of several inches, and the sand is also drenched with sea-water at high
tide. It then lies exposed to the sun and wind, which soon evaporate the water,
and the surface is covered with a white efflorescence of salt. It is then turned over
frequently with the shovel, changing the surface several times a day, till the whole
is perfectly dry. This saline sand is carried to the sheds, and the process repeated
with fresh sand, till a large quantity is collected.</p>
          <p>To make the brine, the dry saline sand is taken out of the sheds and thrown into
small round pits, 2 1/2 feet in diameter and 12 inches deep, the bottoms of which
are lined with hard rammed clay, mixed with straw. The sand is then covered with
sea-water, or with the weaker ley of former operations, and, after standing some
hours, is drawn off into reservoirs or barrels, whence the evaporating-pans are
supplied. The sand is lixiviated a second time, and this ley is reserved for a fresh
portion of saline sand. The boilers used on the western coast of France are about
3 1/2 feet square, and 4 or 6 inches in depth—a charge is worked off in from 2 to 3
hours. Three pans of this size yield together about 50 pounds of salt, but it is of
rather inferior quality for preserving meat.</p>
        </div2>
        <div2 type="method">
          <head>FIFTH METHOD.</head>
          <head>BY BOILING SEA-WATER.</head>
          <p>This method cannot be made <hi rend="italics">economical</hi> except where fuel is very cheap. In
Scotland a very good quality of salt is made in this manner. The boiling processes
are identical with those detailed under the <hi rend="italics">second method</hi>, excepting that, on
account of the weakness of the brine, the <hi rend="italics">first</hi> operation (sludging) is very much
prolonged.</p>
          <p>COST OF BOILING.—Ordinary sea-water contains about 2 1/2 per cent. of its
weight of pure salt. Hence, it follows that 10,000 gallons contain a little more than
38 bushels of salt, of 56 pounds each. Assuming that 85 per cent. of this can be
extracted by boiling, 10,000 gallons of sea-water will yield nearly 32 1/2 bushels
of salt. To boil down this quantity of sea-water will require the combustion of 7 1/3
cords of wood; that is, not quite 4 1/2 bushels of salt to each cord of wood burnt.
When the brine is <hi rend="italics">weaker</hi> than ordinary sea-water, of course the yield will be
proportionally <hi rend="italics">smaller</hi>, and the operations more expensive. To obtain a <hi rend="italics">good
quality</hi> of salt, all the precautions in boiling indicated under the <hi rend="italics">second method</hi>
must be observed.</p>
          <p>The foregoing abstract of the several processes of manufacturing salt from sea-
water has been prepared at the request of a member of the Executive Council of the State of South Carolina.</p>
        </div2>
      </div1>
    </body>
  </text>
</TEI.2>